ISSN 0021-3454 (print version)
ISSN 2500-0381 (online version)
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Issue
vol 67 / February, 2024
Article
UDC 681.3

LASER ACTIVE MEDIUM ON THE BASE OF BISMUTH-DOPED FLUORIDE GLASS ZBLAN

A. N. Romanov
Research Computing Senter, Lomonosov Moscow State University; LLC “Dimonta”;


E. V. Haula
Semenov Institute of Chemical Physics, RAS, Moscow ; Scientist


Z. T. Fattakhova
Semenov Institute of Chemical Physics, RAS, Moscow ;


A. A. Veber
General Physics Institute, RAS, Moscow; Junior Scientist


V. N. Korchak
Semenov Institute of Chemical Physics, RAS, Moscow ; Professor


V. B. Tsvetkov
Prokhorov General Physics Institute of the Russian Academy of Sciences, Moscow, 119991, Russian Federation, ; Deputy Director


V. B. Sulimov
Research Computing Senter, Lomonosov Moscow State University; LLC “Dimonta”;


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Abstract.   Addition of bismuth fluoride BiF3 to ZBLAN fluoride glass with composition (53ZrF4—20BaF2—4LaF3—20NaF—3AlF3) is shown to lead to partial reduction of bismuth fluoride to luminescent subvalent bismuth compounds. The resulting glass is of high optical quality and demonstrates broadband luminescence in Near-IR (1000—1500 nm). The glass is reported to comprise a promising active media for broadband optical amplifiers and tunable lasers. The nature on near-infrared luminescent subvalent bismuth centers in ZBLAN glass is discussed.
Keywords: subvalent bismuth, luminescence, fluoride glasses, optical amplifier.